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A loop-gap resonator for chirality-sensitive nuclear magneto-electric resonance (NMER)

2016

Article

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Direct detection of molecular chirality is practically impossible by methods of standard nuclear magnetic resonance (NMR) that is based on interactions involving magnetic-dipole and magnetic-field operators. However, theoretical studies provide a possible direct probe of chirality by exploiting an enantiomer selective additional coupling involving magnetic-dipole, magnetic-field, and electric field operators. This offers a way for direct experimental detection of chirality by nuclear magneto-electric resonance (NMER). This method uses both resonant magnetic and electric radiofrequency (RF) fields. The weakness of the chiral interaction though requires a large electric RF field and a small transverse RF magnetic field over the sample volume, which is a non-trivial constraint. In this study, we present a detailed study of the NMER concept and a possible experimental realization based on a loop-gap resonator. For this original device, the basic principle and numerical studies as well as fabrication and measurements of the frequency dependence of the scattering parameter are reported. By simulating the NMER spin dynamics for our device and taking the F-19 NMER signal of enantiomer-pure 1,1,1-trifluoropropan-2-ol, we predict a chirality induced NMER signal that accounts for 1%-5% of the standard achiral NMR signal. Published by AIP Publishing.

Author(s): Garbacz, Piotr and Fischer, Peer and Kraemer, Steffen
Journal: J. Chem. Phys.
Volume: 145
Number (issue): 10
Pages: 104201
Year: 2016
Month: September

Department(s): Micro, Nano, and Molecular Systems
Bibtex Type: Article (article)

DOI: 10.1063/1.4962285
State: Published

BibTex

@article{2016garbacz,
  title = {A loop-gap resonator for chirality-sensitive nuclear magneto-electric resonance (NMER)},
  author = {Garbacz, Piotr and Fischer, Peer and Kraemer, Steffen},
  journal = {J. Chem. Phys.},
  volume = {145},
  number = {10},
  pages = {104201},
  month = sep,
  year = {2016},
  month_numeric = {9}
}